Direct Access to Carbenoids from Alkyl and α-Acyloxy Halides for Boron Homologations ( @chemrxiv.org ): chemrxiv.org/doi/full/10.... ( @AThomasLab ).

Lecture of Prof H. Ohmiya @hirohisaohmiya.bsky.social on "Boron-Enabled Radical Chemistry" now starting online ( @synthesis1969.bsky.social Cheminar), introduced by Prof. Martin Oestreich @silicon-martin.bsky.social .

Stepwise B[triple bond, length as m-dash]N bond cleavage by isocyanides: access to the 3-azaborole structural motif ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a... .

The Acylative Kinetic Resolution of 1,2-Azaborine Naphthols ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Synthesis and Selective Carboboration Reactivity of a Flexible P-Stabilized Bromoborenium ( @InorgChemACS ) : pubs.acs.org/doi/10.1021/... ( @lhfa-cnrs.bsky.social ).

Synthesis and Structure of Group 13 POCOP Complexes ( @InorgChemACS ): pubs.acs.org/doi/10.1021/... ( @rebeccamelen.bsky.social , @PaharSanjukta ).

SuzukiMe: A Tactically Mild Methylation Reagent ( @chemrxiv.org ) : chemrxiv.org/doi/full/10.....

Switching Shapes: Reversible Three Species Photoisomerization of Substituted 1,2-Dihydro-1,2-azaborinines ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/... ( @bettingerlab.bsky.social , @wachtveitl-lab.bsky.social , @for-most-5499.bsky.social ).

N–H/P–H bond activation of ammonia, amines and phosphines at a transient borylene ( @BraunschweigLab ): pubs.rsc.org/en/content/a... ( @chemicalscience.rsc.org ).

Tris((4-BMes 2 )phenyl)methanide: a Carbanion with a Delocalized Triple Quinoidal Structure ( @chemicalscience.rsc.org ): pubs.rsc.org/en/Content/A....

A post-doctoral position (topic: main-group chemistry and @boron-chemistry.bsky.social boron chemistry) funded by @erc.europa.eu (ERC Research 🇪🇺 🇧🇪; project B-YOND) is available in the group. Applications until April 15ᵗʰ 🗓️. 🔽See details below.⬇️ Please RT✔️. Link: euraxess.ec.europa.eu/jobs/417016.

Heteronuclear dual-atom insertion into oxetanes via frustrated Lewis pair activation ( @mjkoh87.bsky.social ): www.nature.com/articles/s44... ( @natsynth.nature.com ).

Temperature-Responsive Near-Infrared Emission Enabled by Reversible π-Umpolung with an Alkenyl-Strapped Diarylboryl Unit ( @yamaguchi-lab-nu.bsky.social ): onlinelibrary.wiley.com/doi/full/10.... ( @angewandtechemie.bsky.social ).

Lateral Boron-Doping Intensifies Diradical State and Stabilizes Spins of peri-Acenoacene: A Nanographene Diradicaloid with Absorption beyond 1300 nm ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....

Conformationally Driven Dual Fluorescence Properties of Higher Heteroacenes With Periodically Incorporated Boron Atoms ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

Potassium N-Borylisocyanamide: Synthesis, Structure, and Its Utilization as an Amino and Cyano Transfer Reagent ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....

Light-Driven Radical Catch-and-Release with BODIPY Photocages ( @chemrxiv.org ): chemrxiv.org/doi/full/10....

1,4-Bromoboration of Nitroalkenes ( @chemrxiv.org ): chemrxiv.org/doi/full/10.....

Substituent effects on o-carborane reactivity with cyclic (alkyl)(amino)carbene (@dobrovetskyg.bsky.social): pubs.rsc.org/en/Content/A... (@inorgchemfront.rsc.org).

Redox- and Protonation-Tunable Diboraheptacenes (@judywuchem.bsky.social, @rjgilliard.bsky.social, @gilliardgroup.bsky.social): pubs.acs.org/doi/10.1021/... (@jacs.acspublications.org).

✨Special Topic Dedicated To Prof. Paul Knochel✨ Berionni & co-workers @dr-berionni.bsky.social report transition-metal-free #borylation of electron-poor arenes and polyaromatics using a 9-boratriptycene pyramidal boron Lewis #superacid💡 #OpenAccess 👉 buff.ly/eRLkiaG

Stereospecific alkyl–alkyl cross-coupling of boronic esters (@nature.com, @nature.com.web.brid.gy): www.nature.com/articles/s41... (James P. Morken).

Iron-borane catalyzed carbonyl hydroboration and isolation of an iron(I)-ketyl radical ( @dr-dwillcox.bsky.social ): www.nature.com/articles/s41... ( @nature.com , @nature.com.web.brid.gy ).

Perdefluorinative borylation of perfluoroalkyl and gem-difluoroalkenes ( @chemrxiv.org ): chemrxiv.org/doi/full/10.....

Borane Catalysed Annulative Sulfenylation of Internal Alkynes: Towards the Synthesis and Study of Highly Unsaturated Heterocycles ( @rebeccamelen.bsky.social ): chemrxiv.org/doi/10.26434... ( @chemrxiv.org ).

The Important Role of Carbonyl in Accelerating Reverse Intersystem Crossing for Selenium-Based Organoboron Narrowband Blue Emitters ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

Selective Reductions of Complex Pyridines via NTf-Pyridinium Salts: www.thieme-connect.com/products/ejo... (@synthesis1969.bsky.social).

Diboron- and digermanium-doped dihydrodibenzohexacenes: Ge–B exchange to access boron-doped extended acenes ( @gilliardgroup.bsky.social, @cromeronieto.bsky.social) : pubs.rsc.org/en/content/a... ( @chemicalscience.rsc.org ).

A New Class of Customisable Stable Boronic Ester Assembly ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Synthesis of Transition-Metal–Boryl Complexes from Diboron Reagents (@synthesis1969.bsky.social): www.thieme-connect.com/products/ejo....

Come join our team! 🧪🥼Two PhD positions available in sustainable catalysis using frustrated Lewis pairs as part of ERC funded grant. Fully funded for EU and UK students. @erc.europa.eu @cardiffuni.bsky.social ⬇️⬇️⬇️ www.findaphd.com/phds/project...

Thiol-Free Sulfenylation Redefined: A Single-Atom Transfer Pathway to Symmetrical Di(hetero)arylthioethers via B(C6F5)3 Catalysis ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/... ( @rebeccamelen.bsky.social, @cardiffuni.bsky.social ).

Unraveling the positive effect of twisted helicene structure on narrowband electroluminescence ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a...

Room Temperature Phosphorescence from a Benzothiophene-based N-B-N Multi-Resonance Core (@ezc-group.bsky.social): pubs.rsc.org/en/Content/A...

Widely-used boronic esters as synthetically-versatile directing groups for C–H activation and hydrogen isotope exchange ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

An Organoborate Monoxide Radical ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/... ( @ahmadmasarwa.bsky.social ).

Catellani-Inspired BN-Aromatic Expansion: A Versatile Tool toward π-Extended 1,2-Azaborines with Tunable Photosensitizing Properties ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....

Mallory-Type Reactivity of 1,2-Dihydroazaborinines: 6π-Electrocyclization-[1,5]-H Shift Cascade toward BN-Doped Polycyclic Frameworks ( @pubs.acs.org ): pubs.acs.org/doi/10.1021/....

Diastereoselective Synthesis of cis-α,α′-Disubstituted Cyclic Ethers via Borane-Catalyzed Reductive Cyclization of Diketones ( @pubs.acs.org ): pubs.acs.org/doi/full/10.... ( @jmasrosello.bsky.social ).

Our last paper of the year: Electrophilic C(sp2)−H Borylation of Nonactivated Arenes with Pyramidal Boron Lewis Superacids ❄️. Just published in @synthesis1969.bsky.social : special issue dedicated to Paul Knochel. 🎁 @boron-chemistry.bsky.social. Congrats Nicolas, Arnaud & Baptiste.

Aminoboranes as Rationally Tuned Organic Photosensitizers for Energy Transfer Catalysis ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

A Boron-Doped Buckybowl with a C42B2 Core: Synthesis, Crystal Structure, and Optoelectronic Properties ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

Stereodivergent Synthesis of Three Contiguous Stereogenic Centers by Cu/Ir-Catalyzed Borylallylation ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/... (Suman Das, @stanna-dorn.bsky.social , M. Kevin Brown ).

Unusual nitrene reactivity: imine formation in the photochemical reaction of a borylnitrene with ethene ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Transient Bis(Carboranyl)boryl Anions ( @chemrxiv.org ): chemrxiv.org/engage/chemr....

Tris(pentafluorophenyl)borane Catalyzed Stereoselective Synthesis of β-O-Aryl Glycosides from Armed and Disarmed Glycosylimidate Donors ( @pubs.acs.org ): pubs.acs.org/doi/10.1021/....

Metal-Free Radical Borylations: Mechanisms, Catalytic Strategies, and Synthetic Applications ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

N-centered, yet persistent: isolation of N2O-based radicals through FLP-type stabilization ( @lcc-smac.bsky.social ): pubs.rsc.org/en/content/a... ( @chemicalscience.rsc.org ).

Access to allyl-gem-difluorides via allylation and Cope rearrangement ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....