Copper-Catalyzed Asymmetric Hydroboration of Alkynes to C-N Axially Chiral Azaborines via Dynamic Kinetic Resolution ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/... .

Accessing chiral NHC-boranes by abstraction of C6F5 from the B(C6F5)4− weakly coordinating anion ( @dr-berionni.bsky.social ; @b-kajetan.bsky.social ): pubs.rsc.org/en/content/a... ( @daltontrans.rsc.org ).

Goldilocks boronic esters: optimized properties through understanding hydrolysis kinetics ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Zerovalent transition-metal inverse-sandwich complexes of a diborataanthracene dianion ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a... ( @LabBraunschweig ).

Extending the Boundaries With Electron-Rich Tris(pyridyl)borates in Classical Silver and Gold Carbonyl Complexes ( @chemistryeurope.bsky.social ): chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/... ( @isra-group.bsky.social ).

Three Component Thio- and Carboboration of Alkynes: A Modular Route to Functionalised Bicyclic Boronates ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/... ( @InglesonMike )

Diastereoselective and Chemically Reversible C–C Bond Formation Mediated by an (N-heterocyclic)boryloxy Aluminyl Compound ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/... ( @DebotraSarkar , @GroupAldridge ).

Toposelective on-surface synthesis of curved π-extended oligomers based on bowl-shaped aromatics ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a... ( @marta_gomezg , @labella_jorge , @jonasbjork.bsky.social , @TTorresGroup ).

A Crystalline Dioxaborirane through BoryleneActivation of Dioxygen ( @researchsquare ): www.researchsquare.com/article/rs-9... ( @LLL-lab-SUSTech ).

Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation ( @martinez_a_j , @kraemergroup.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/... ( @angewandtechemie.bsky.social ).

[Os(η5-B5H10)2]: A carbon-free analog of ferrocene ( @JemmisLab ): science.org/doi/10.1126/... ( @science.org ).

BODIPY bridged bicyclic nanoring : www.sciencedirect.com/science/arti...

BX3-Mediated Directed Electrophilic Borylation: Advances, Applications, and Mechanistic Insights (Accounts of Chemical Research @acs.org ): pubs.acs.org/doi/10.1021/....

Periodic Influences on the Charge-Transfer and Radical Ion Pair Formation in Pnictogen-Based Frustrated Lewis Pairs ( @chrisslootweg.bsky.social ): chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/... ( @chemistryeurope.bsky.social ).

Borane Catalysed Annulative Sulfenylation of Internal Alkynes: Towards the Synthesis and Study of Fused Heterocycles ( @rebeccamelen.bsky.social ): pubs.rsc.org/en/Content/A... ( @chemicalscience.rsc.org ).

Reactions of diazoboranes with oxygen enables the synthesis and isolation of dioxaboriranes ( @rjgilliard.bsky.social , @gilliardgroup.bsky.social ): www.nature.com/articles/s41... ( @natchem.nature.com ).

Zinc Redox Catalysis in the Photochemical Borylation of Fluorocarbons ( @chemrxiv.org ): chemrxiv.org/doi/full/10.... ( @crimmingroup.bsky.social ).

Metal-free deoxygenative borylation of pyrazinyl ethers via an unusual boron-walking mechanism ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Direct Access to Carbenoids from Alkyl and α-Acyloxy Halides for Boron Homologations ( @chemrxiv.org ): chemrxiv.org/doi/full/10.... ( @AThomasLab ).

Lecture of Prof H. Ohmiya @hirohisaohmiya.bsky.social on "Boron-Enabled Radical Chemistry" now starting online ( @synthesis1969.bsky.social Cheminar), introduced by Prof. Martin Oestreich @silicon-martin.bsky.social .

Stepwise B[triple bond, length as m-dash]N bond cleavage by isocyanides: access to the 3-azaborole structural motif ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a... .

The Acylative Kinetic Resolution of 1,2-Azaborine Naphthols ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Synthesis and Selective Carboboration Reactivity of a Flexible P-Stabilized Bromoborenium ( @InorgChemACS ) : pubs.acs.org/doi/10.1021/... ( @lhfa-cnrs.bsky.social ).

Synthesis and Structure of Group 13 POCOP Complexes ( @InorgChemACS ): pubs.acs.org/doi/10.1021/... ( @rebeccamelen.bsky.social , @PaharSanjukta ).

SuzukiMe: A Tactically Mild Methylation Reagent ( @chemrxiv.org ) : chemrxiv.org/doi/full/10.....

Switching Shapes: Reversible Three Species Photoisomerization of Substituted 1,2-Dihydro-1,2-azaborinines ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/... ( @bettingerlab.bsky.social , @wachtveitl-lab.bsky.social , @for-most-5499.bsky.social ).

N–H/P–H bond activation of ammonia, amines and phosphines at a transient borylene ( @BraunschweigLab ): pubs.rsc.org/en/content/a... ( @chemicalscience.rsc.org ).

Tris((4-BMes 2 )phenyl)methanide: a Carbanion with a Delocalized Triple Quinoidal Structure ( @chemicalscience.rsc.org ): pubs.rsc.org/en/Content/A....

A post-doctoral position (topic: main-group chemistry and @boron-chemistry.bsky.social boron chemistry) funded by @erc.europa.eu (ERC Research 🇪🇺 🇧🇪; project B-YOND) is available in the group. Applications until April 15ᵗʰ 🗓️. 🔽See details below.⬇️ Please RT✔️. Link: euraxess.ec.europa.eu/jobs/417016.

Heteronuclear dual-atom insertion into oxetanes via frustrated Lewis pair activation ( @mjkoh87.bsky.social ): www.nature.com/articles/s44... ( @natsynth.nature.com ).

Temperature-Responsive Near-Infrared Emission Enabled by Reversible π-Umpolung with an Alkenyl-Strapped Diarylboryl Unit ( @yamaguchi-lab-nu.bsky.social ): onlinelibrary.wiley.com/doi/full/10.... ( @angewandtechemie.bsky.social ).

Lateral Boron-Doping Intensifies Diradical State and Stabilizes Spins of peri-Acenoacene: A Nanographene Diradicaloid with Absorption beyond 1300 nm ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....

Conformationally Driven Dual Fluorescence Properties of Higher Heteroacenes With Periodically Incorporated Boron Atoms ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

Potassium N-Borylisocyanamide: Synthesis, Structure, and Its Utilization as an Amino and Cyano Transfer Reagent ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....

Light-Driven Radical Catch-and-Release with BODIPY Photocages ( @chemrxiv.org ): chemrxiv.org/doi/full/10....

1,4-Bromoboration of Nitroalkenes ( @chemrxiv.org ): chemrxiv.org/doi/full/10.....

Substituent effects on o-carborane reactivity with cyclic (alkyl)(amino)carbene (@dobrovetskyg.bsky.social): pubs.rsc.org/en/Content/A... (@inorgchemfront.rsc.org).

Redox- and Protonation-Tunable Diboraheptacenes (@judywuchem.bsky.social, @rjgilliard.bsky.social, @gilliardgroup.bsky.social): pubs.acs.org/doi/10.1021/... (@jacs.acspublications.org).

✨Special Topic Dedicated To Prof. Paul Knochel✨ Berionni & co-workers @dr-berionni.bsky.social report transition-metal-free #borylation of electron-poor arenes and polyaromatics using a 9-boratriptycene pyramidal boron Lewis #superacid💡 #OpenAccess 👉 buff.ly/eRLkiaG

Stereospecific alkyl–alkyl cross-coupling of boronic esters (@nature.com, @nature.com.web.brid.gy): www.nature.com/articles/s41... (James P. Morken).

Iron-borane catalyzed carbonyl hydroboration and isolation of an iron(I)-ketyl radical ( @dr-dwillcox.bsky.social ): www.nature.com/articles/s41... ( @nature.com , @nature.com.web.brid.gy ).

Perdefluorinative borylation of perfluoroalkyl and gem-difluoroalkenes ( @chemrxiv.org ): chemrxiv.org/doi/full/10.....

Borane Catalysed Annulative Sulfenylation of Internal Alkynes: Towards the Synthesis and Study of Highly Unsaturated Heterocycles ( @rebeccamelen.bsky.social ): chemrxiv.org/doi/10.26434... ( @chemrxiv.org ).

The Important Role of Carbonyl in Accelerating Reverse Intersystem Crossing for Selenium-Based Organoboron Narrowband Blue Emitters ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

Selective Reductions of Complex Pyridines via NTf-Pyridinium Salts: www.thieme-connect.com/products/ejo... (@synthesis1969.bsky.social).

Diboron- and digermanium-doped dihydrodibenzohexacenes: Ge–B exchange to access boron-doped extended acenes ( @gilliardgroup.bsky.social, @cromeronieto.bsky.social) : pubs.rsc.org/en/content/a... ( @chemicalscience.rsc.org ).

A New Class of Customisable Stable Boronic Ester Assembly ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Synthesis of Transition-Metal–Boryl Complexes from Diboron Reagents (@synthesis1969.bsky.social): www.thieme-connect.com/products/ejo....

Come join our team! 🧪🥼Two PhD positions available in sustainable catalysis using frustrated Lewis pairs as part of ERC funded grant. Fully funded for EU and UK students. @erc.europa.eu @cardiffuni.bsky.social ⬇️⬇️⬇️ www.findaphd.com/phds/project...

Thiol-Free Sulfenylation Redefined: A Single-Atom Transfer Pathway to Symmetrical Di(hetero)arylthioethers via B(C6F5)3 Catalysis ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/... ( @rebeccamelen.bsky.social, @cardiffuni.bsky.social ).