Diastereoselective Synthesis of cis-α,α′-Disubstituted Cyclic Ethers via Borane-Catalyzed Reductive Cyclization of Diketones ( @pubs.acs.org ): pubs.acs.org/doi/full/10.... ( @jmasrosello.bsky.social ).

Our last paper of the year: Electrophilic C(sp2)−H Borylation of Nonactivated Arenes with Pyramidal Boron Lewis Superacids ❄️. Just published in @synthesis1969.bsky.social : special issue dedicated to Paul Knochel. 🎁 @boron-chemistry.bsky.social. Congrats Nicolas, Arnaud & Baptiste.

Aminoboranes as Rationally Tuned Organic Photosensitizers for Energy Transfer Catalysis ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

A Boron-Doped Buckybowl with a C42B2 Core: Synthesis, Crystal Structure, and Optoelectronic Properties ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

Stereodivergent Synthesis of Three Contiguous Stereogenic Centers by Cu/Ir-Catalyzed Borylallylation ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/... (Suman Das, @stanna-dorn.bsky.social , M. Kevin Brown ).

Unusual nitrene reactivity: imine formation in the photochemical reaction of a borylnitrene with ethene ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Transient Bis(Carboranyl)boryl Anions ( @chemrxiv.org ): chemrxiv.org/engage/chemr....

Tris(pentafluorophenyl)borane Catalyzed Stereoselective Synthesis of β-O-Aryl Glycosides from Armed and Disarmed Glycosylimidate Donors ( @pubs.acs.org ): pubs.acs.org/doi/10.1021/....

Metal-Free Radical Borylations: Mechanisms, Catalytic Strategies, and Synthetic Applications ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

N-centered, yet persistent: isolation of N2O-based radicals through FLP-type stabilization ( @lcc-smac.bsky.social ): pubs.rsc.org/en/content/a... ( @chemicalscience.rsc.org ).

Access to allyl-gem-difluorides via allylation and Cope rearrangement ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Catalytic Enantioselective [6π] Photocyclization Reactions by Chromophore Activation with a Chiral Lewis Acid ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....

Boraindenes as versatile precursors to benzannulated boron heterocycles ( @LabBraunschweig ): pubs.rsc.org/en/content/a... ( @chemicalscience.rsc.org ).

Bulky Phosphine Ligands Promote Palladium-Catalyzed Protodeboronation ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/... ( @aspuru.bsky.social , @thematterlab.bsky.social )

Electronic Activation Enables the Borylation of Alkyl C–H Bonds in Saturated Nitrogen Heterocycles ( @hartwiggroup.bsky.social ): pubs.acs.org/doi/10.1021/... ( @jacs.acspublications.org ).

A Crystalline Phosphorus-Substituted Borinium Ion: Double Dihydrogen Activation by an Ambiphilic Inorganic Allene ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Regioselective C(sp3)–H borylation via a diarylboryl anion surrogate in sp2–sp3 diboranes ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

C3-Symmetric Borabuckybowl Featuring a Pyramidal-like sp2 Boron Atom for Advanced Electronics and Optical Functions ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....

Fused 3D Boron Heterocycles via EnT Catalysis: Synthesis, Modification and Validation as Beta-Lactamase Inhibitors: pubs.rsc.org/en/content/a... ( @chemicalscience.rsc.org ).

Deep-Red to Near-Infrared Light-Driven Radical Generation from Organoboron Compounds via Ligand-Induced Direct Excitation Catalysis (@hirohisaohmiya.bsky.social): pubs.acs.org/doi/10.1021/... (@jacs.acspublications.org).

A Crystalline Monomeric Diboryl Diazene ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/... ( @llliugroup.bsky.social ).

Direct Boron-10 Access: Nickel-Catalyzed Reductive C(sp2)─10B Coupling Utilizing 10BF3 ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

Boron-enabled Stereoselective Synthesis of Polysubstituted Housanes ( @Johnjmol ): chemrxiv.org/engage/chemr... ( @chemrxiv.org ).

Synthesis of Degradable Polyimines Through Deborylative Polycondensation ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/10.1002/....

Synthesis and Optical Properties of Unsymmetric Aromatically π-Extended BODIPY (@pubs.acs.org): pubs.acs.org/doi/full/10.... (@mathiassenge.bsky.social).

Our latest article on B chemistry @boron-chemistry.bsky.social is featured on the cover of ChemistryEurope @chemistryeurope.bsky.social (chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1...) : from new Lewis superacids/pyridine pairs to unusual binding modes with WCAs and B-N bis-triptycenes.

Colorimetric indication of hidden catalysis (with BH3) ( @spthomasgroup.bsky.social ): www.nature.com/articles/s41... ( @natchem.nature.com ).

Antiaromatic Nanographenes by BODIPY-Fusion Strategy ( @chemrxiv.org ): chemrxiv.org/engage/chemr....

One-Electron Boron–Carbon Triel Bonding ( @francoisgabbai.bsky.social ): pubs.acs.org/doi/10.1021/... ( @jacs.acspublications.org ).

A borindolizine platform for the design of fluorophores with tun-able emissions (@chemicalscience.rsc.org): pubs.rsc.org/en/content/a... ( @andreiyudin.bsky.social ).

Simple, one-step syntheses of tri- and tetracyclic B,N,S-heterocycles from reactions of a diboracumulene with thiols ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

Directed Secondary C(sp3)–H Borylation by a Phenoxyimine Iridium Catalyst at Room Temperature (@pubs.acs.org): pubs.acs.org/doi/10.1021/....

Sequential Carboborylation–Suzuki Coupling of α,β-Unsaturated Tosylhydrazones: A Dual CC Bond-Forming Strategy for Molecular Diversification ( @chemistryeurope.bsky.social ): chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/....

We are ready to welcome >100 participants from 12 countries and 32 institutions at the #MGERC2025 conference at the University of Namur 🇧🇪 next week (@mgerc-unamur.bsky.social). Many thanks to our speakers and sponsors, have a good trip to Namur & see you on Monday.

A Crystalline Boravinylidene from an Arrested Hydroboration Reaction ( @boron11.bsky.social ): pubs.acs.org/doi/10.1021/... ( @jacs.acspublications.org ).

Stable BF₂ Boracycles as Versatile Reagents for Selective Ortho C–H Functionalization (@chemrxiv.org): chemrxiv.org/engage/chemr... ( @sundenlab ).

Arylboration of Cyclic Enones via Cooperative Copper/Palladium Catalysis (@pubs.acs.org) : pubs.acs.org/doi/10.1021/... (@thenewmanlab.bsky.social, @piyaschem.bsky.social).

Modular α-Functionalization of Bowl-Shaped Subphthalocyanine Aromatics (@pubs.acs.org): pubs.acs.org/doi/10.1021/....

Donor–Acceptor–Acceptor-Type Near-Infrared Fluorophores Featuring Thieno[3,2-b]thiophene S,S-Dioxide and Diarylboryl Units as Dual Acceptors ( @pubs.acs.org ) : pubs.acs.org/doi/10.1021/....

Reversible Electron Transfer in the Formation of Radical Anionic and Dianionic 1,4-Diborabutatrienes ( @jacs.acspublications.org ): pubs.acs.org/doi/10.1021/....

Benzo-extended N^N^N-chelated tetracoordinate boron hetero[8]helicene featuring an inner N–B–N helical rim for circularly polarized TADF (@jmaterchem.rsc.org): pubs.rsc.org/en/content/a...

Catalytic Borylation of Poly(vinyl chloride) Produces Adhesive Materials ( @hartwiggroup.bsky.social ): pubs.acs.org/doi/10.1021/... ( @jacs.acspublications.org ).

‪Phototoxicity of Hydroxymethyl-BODIPYs: Are Photocages That Innocent? (@gassergroup.bsky.social‬, @kirillkuznetsov.bsky.social, @arthurhwinter.bsky.social): pubs.rsc.org/en/Content/A... (@chemicalscience.rsc.org).

Sorting by Proximity-Effect: Direct Ester to Ether Deoxygenation Using Fiddler Crab-Type Borane Catalysts (@soosgroup.bsky.social): chemrxiv.org/engage/chemr... (@chemrxiv.bsky.social).

Synthesis, Properties, and Chemoselective Reactions of an AlH–BH Functional Group (@crimmingroup.bsky.social): chemrxiv.org/engage/chemr... (@chemrxiv.bsky.social).

Dual 1,2-Migration-Enabled β-Boryl Amide Synthesis ( @pubs.acs.org ): pubs.acs.org/doi/abs/10.1....

Stable yet Strongly Lewis-Acidic Anions Enabling Cooperative Catalysis with Cationic Transition Metal Complexes ( @angewandtechemie.bsky.social ): onlinelibrary.wiley.com/doi/abs/10.1....

Modular arene functionalization by differential 1,2-diborylation (@donglab.bsky.social): nature.com/articles/s41... (@nature.com).

Highly Antiaromatic Naphtho-1,2-Diboretes as Precursors for Tunable, Unsymmetrical 1,4-Diboraanthracenes (@HolgerBraunschweig): pubs.acs.org/doi/10.1021/... (@jacs.acspublications.org).

Diastereoselective Synthesis of Cyclopropyl Diboronates via 1,2-Boronate Rearrangement (@angewandtechemie.bsky.social): onlinelibrary.wiley.com/doi/10.1002/...