Check out this preprint from @goldmangroup.bsky.social on (Pybox)Os-catalyzed tail-to-tail homo/hetero coupling of α-olefins. Striking mechanistic differences from isoelectronic (Phebox)Ir shed light on fundamental steps of oxidative addition and reductive elimination. doi.org/10.26434/che...

One of our group members, @sohamchakraborty.bsky.social will be presenting tomorrow at #ACSSpring2025! Stop by and hear about his work on alkane dehydrogenation using Pybox-ligated metal complexes

Check out this work from @goldmangroup.bsky.social in JACS @acsjacs.bsky.social telling an interesting story on bizarre selectivities for alkane dehydrogenation, H/D exchange and much more. Congrats to our very own Ashish @ashishchemist.bsky.social, Faraj, Tom and Alan @catalyzer.bsky.social

Great work by @ashishchemist.bsky.social and Prof. Faraj Hasanayn (AUB) demonstrating an unprecedented mechanism for double C-H activation of alkanes leading to dehydrogenation (and the reverse, olefin hydrogenation) and H/D exchange all with bizarre selectivity.

Check out this preprint go.shr.lc/4f6mlGG by @ashishchemist.bsky.social of @goldmangroup.bsky.social reporting (iPrPCP)IrH+ for dehydrogenation, hydrogenation & H/D exchange with unusual selectivity. Proceeding via a novel mechanism of C-H addition and beta-H elimination. @catalyzer.bsky.social