Ashish Parihar
@ashishchemist.bsky.social
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📥 66
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reposted by
Ashish Parihar
Alan Goldman
about 1 month ago
Outstanding work by
@ashishchemist.bsky.social
and the team yields some promising catalysis and raises some extraordinarily fundamental organometallic questions!
add a skeleton here at some point
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reposted by
Ashish Parihar
Goldman Group
about 1 month ago
Check out this preprint from
@goldmangroup.bsky.social
on (Pybox)Os-catalyzed tail-to-tail homo/hetero coupling of α-olefins. Striking mechanistic differences from isoelectronic (Phebox)Ir shed light on fundamental steps of oxidative addition and reductive elimination.
doi.org/10.26434/che...
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reposted by
Ashish Parihar
Goldman Group
7 months ago
Check out this work from
@goldmangroup.bsky.social
in JACS
@acsjacs.bsky.social
telling an interesting story on bizarre selectivities for alkane dehydrogenation, H/D exchange and much more. Congrats to our very own Ashish
@ashishchemist.bsky.social
, Faraj, Tom and Alan
@catalyzer.bsky.social
add a skeleton here at some point
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reposted by
Ashish Parihar
Alan Goldman
11 months ago
Great work by
@ashishchemist.bsky.social
and Faraj Hasanayn (AUB) demonstrating an unprecedented mode of alkane C-H activation leading to alkane dehydrogenation, olefin hydrogenation, and H Isotope Exchange with bizarre selectivity.
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reposted by
Ashish Parihar
Goldman Group
11 months ago
Check out this preprint
go.shr.lc/4f6mlGG
by
@ashishchemist.bsky.social
of
@goldmangroup.bsky.social
reporting (iPrPCP)IrH+ for dehydrogenation, hydrogenation & H/D exchange with unusual selectivity. Proceeding via a novel mechanism of C-H addition and beta-H elimination.
@catalyzer.bsky.social
loading . . .
Alkane Dehydrogenation and H/D Exchange by a Cationic Pincer-Ir(III) Hydride: A Novel Mechanism of C-H Addition and 𝛽-H Elimination Leads to Unprecedented Selectivity
We report that the cationic iridium complex (iPrPCP)IrH+ undergoes addition of alkane C-H bonds, which is manifested by catalytic alkane transfer-dehydrogenation to give alkenes and by hydrogen isotop...
https://go.shr.lc/4f6mlGG
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