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QD-NWs are grown in CNR Nanoscience in Pisa by Giada Bucci supervised by Valentina Zannier in the group of Lucia Sorba via vapour-liquid-solid mode in chemical beam epitaxy pubs.acs.org/doi/10.1021/... www.nano.cnr.it/researcher-p... This is a part of QCEED project www.qceed.eu #QTorch #QuanTour

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Zincblende InAsxP1–x/InP Quantum Dot Nanowires for Telecom Wavelength Emission InAsxP1–x quantum dots (QDs) in InP nanowires (NWs) have been realized as a platform for emission at telecom wavelengths. These QDs are typically grown in NWs with the wurtzite crystal phase, but in this case, ultrathin diameters are required to achieve defect-free heterostructures, making the structures less robust. In this work, we demonstrate the growth of pure zincblende InAsxP1–x QDs in InP NWs, which enabled an increase in NW diameters to about 45 nm, achieved by employing Au-assisted vapor liquid solid growth in a chemical beam epitaxy system. We studied the growth of InP/InAsxP1–x heterostructures with different compositions to control the straight growth along the ⟨100⟩ direction and to tune the emission wavelength. Interestingly, we found that the growth mechanism for pure InAs QDs is different compared to that for InAsxP1–x alloy QDs. This allowed us to optimize different growth protocols to achieve straight growth of the final QD NWs. We successfully obtained the growth of InAsxP1–x QDs with a composition in the range of x = 0.24–1.00. By means of microphotoluminescence measurements, we demonstrate the tunability of the emission in dependence of the InAsxP1–x QD composition and morphology, remarkably observing an emission at the telecom O-band for a 10 nm thick QD with 80% of As content. https://pubs.acs.org/doi/10.1021/acsami.4c00615