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Substituting Cyclohexyl with Phenyl at Phosphorus Makes a NiP2N2 Molecular Catalyst Active for Hydrogen Evolution in Alkaline Conditions at Low Overvoltage Among the large family of mononuclear bis-diphosphine nickel catalysts with pendant amines, the so-called NiCyArg complex, with a cyclohexyl group at the phosphine and an arginine substituted amine, h... https://pubs.acs.org/doi/10.1021/jacs.5c11615