Jiaxiang Chu
@jiaxiangchu.bsky.social
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Organometallic chemistry at University of Chinese Academy of sciences
reposted by
Jiaxiang Chu
LLLiu Group
17 days ago
Our team has isolated a metal-free crystalline isodiazomethyl anion, a key carbon/nitrogen motif long absent in synthetic chemistry. Dive into our
@natsynth.nature.com
paper for all the details. Congrats to Hongyu and Jiancheng!
www.nature.com/articles/s44...
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A crystalline isodiazomethyl anion - Nature Synthesis
A boryl-isodiazomethyl anion featuring a bent eneyne-type B=NāNā”C scaffold is isolated and structurally characterized. The highly nucleophilic boron-bound nitrogen centre makes this species an effecti...
https://www.nature.com/articles/s44160-025-00981-7
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reposted by
Jiaxiang Chu
C&EN (Chemical & Engineering News)
about 2 months ago
Molecules of the year 2025 C&EN editorsā annual round-up of spectacular molecules weāve covered in the past year:
cen.acs.org/synthesis/Mo...
#chemsky
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Our work on Carbocation-Coupled Electron Transfer is now in Inorg Chem. An α-ferrocenylmethylium isnāt just a carbocationāitās a masked primary alkyl radical that couples with radicals, adds across Ļ-bonds and CāH-activates heterocycles. New radical route to CāX bonds.
pubs.acs.org/doi/10.1021/...
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https://pubs.acs.org/doi/10.1021/acs.inorgchem.5c04581
3 months ago
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reposted by
Jiaxiang Chu
Alex Speed
4 months ago
If you were going to teach a class involving photoredox chemistry, and metallophotoredox chemistry, to grad students, what would your must-have reviews be?
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reposted by
Jiaxiang Chu
Harder Research Group
4 months ago
TIRE CHANGE: First Mg(I) complex with a Cp* ligand enables facile ligand exchange. Reaction with RONa gives (BDI)Mg-MgOR and Cp*Na. This paves the way for syntheses of many new asymmetric Mg(I) complexes. @angew_chem
onlinelibrary.wiley.com/doi/epdf/10....
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reposted by
Jiaxiang Chu
C&EN (Chemical & Engineering News)
6 months ago
For the first time, researchers have created an all-carbon molecular ring that is stable in solution at room temperature, with a bit of supramolecular support.
cen.acs.org/physical-che...
#chemsky
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reposted by
Jiaxiang Chu
Heavily Into The World Of Magnets
7 months ago
Life as an analytical chemist is funny.
#ChemSky
Me: look at that weird peak! User: oh no i don't want to see that weird peak Me: look at this impurity peak increasing over time! User: oh no i don't want to see that peak increasing Me: wow this molecule fell apart in an interesting way! User: š
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Our work on benzene ring opening was featured by C&EN, and we are proud of it!
add a skeleton here at some point
7 months ago
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reposted by
Jiaxiang Chu
Harder Research Group
7 months ago
A Ca(I) synthon with bridging N2 is key to the synthesis of homometallic Ca peroxide and oxide complexes. In solution, the Ca oxide complex decomposes even at -80 C. It can only be prepared in the solid state. @ChemCommun @RoySocChem
shorturl.at/AUoWM
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reposted by
Jiaxiang Chu
Matthew Evans
7 months ago
Happy to share that our paper entitled "Neutral P4 coordination and reduction at alkaline earth metal centers" is now online in
@cp-chem.bsky.social
! Here is a short animated video to accompany this work š§Ŗš
tinyurl.com/23vbtuju
#ozchem
#scicomm
#blender
#maingroupchem
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Our work on the room-temperature ring-opening of benzene is now published in JACS. Great teamwork and thanks for the kind comments from the reviewers!
pubs.acs.org/doi/10.1021/...
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Room Temperature Ring Opening of Benzene by Four-Electron Reduction and Carbonylation
Cleaving a benzene ring under mild conditions requires disrupting its aromaticity, which is a significant challenge in modern chemistry. Although the generation of cyclic products from cleaving benzen...
https://pubs.acs.org/doi/10.1021/jacs.5c08414
8 months ago
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reposted by
Jiaxiang Chu
Christian Limberg
10 months ago
Call For Papers for Special Inorganic Chemistry Issue āProton-Coupled Electron Transfer in Coordination Chemistryā
axial.acs.org/inorganic-ch...
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reposted by
Jiaxiang Chu
Stu Cantrill
10 months ago
Nature Communications is looking to hire an organic chemist ā more details in the link below
#Chemsky
#Chemjobs
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Associate or Senior Editor (Organic Chemistry), Nature Communications
Job Title: Associate or Senior Editor (Organic Chemistry), Nature Communications Organisation:āÆNature Portfolio Locations: Jersey City, London, New York, Philadelphia or Washington DC - hybrid working...
https://springernature.wd3.myworkdayjobs.com/SpringerNatureCareers/job/London/Associate-or-Senior-Editor--Organic-Chemistry---Nature-Communications_JR102692
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