LLLiu Group
@llliugroup.bsky.social
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The LLL group at SUSTech since 2020. Main group chemistry. Views by Leo. He/Him/His
Weāve been quiet for a while, but hereās something exciting: hot off the press: a crystalline monomeric diboryl diazene
@jacs.acspublications.org
pubs.acs.org/doi/10.1021/...
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A Crystalline Monomeric Diboryl Diazene
Azo compounds (RāNāNāRā²) are a foundational class of nitrogen-containing molecules. In contrast to the bench-stability of many azo derivatives, monomeric diboryl diazenes (R2BNāNBR2) have long eluded ...
https://pubs.acs.org/doi/10.1021/jacs.5c14754
about 1 month ago
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reposted by
LLLiu Group
Nature
6 months ago
Nature research paper: Metal-centred planar [15]annulenes.
https://go.nature.com/3YqZj70
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Metal-centred planar [15]annulenes - Nature
An aromatic metallo-annulene, comprising a 15-carbon macrocycle enclosing an osmium complex, with the metal residing within the plane of the macrocycleĀ is reported.
https://go.nature.com/4dgxsNb
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Now online: Our latest publication on Click Chemistry of a Diazomethyl Anion with Unsaturated Bonds in Chinese Journal of Chemistry 2025 Emerging Investigators Issue
onlinelibrary.wiley.com/doi/10.1002/...
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Click Chemistry: Reactions of a Diazomethyl Anion with Unsaturated Bondsā
We report facile [3+2] cycloaddition reactions utilizing potassium diazaphospholidinyl diazomethylide as an electron-rich 1,3-dipole, reacting with various dipolarophiles. The regioselectivity of the...
https://onlinelibrary.wiley.com/doi/10.1002/cjoc.70026
7 months ago
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We are honored!
add a skeleton here at some point
7 months ago
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Congratulations to Xue-Yi and the team for their efforts in isolating silagermenides and uncovering their unconventional reactivity profiles. This achievement has been accepted for publication
@angewandtechemie.bsky.social
āhttps://onlinelibrary.wiley.com/doi/10.1002/anie.202505940
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Crystalline Silagermenides as Powerful Synthons: Unraveling ĻāBonding and Lone Pair Effects in the Multiple Bonds of Heavier Main Group Analogs of the Vinyl Anion
Compared to common vinyl anions, their heavier heteronuclear analog, silagermenides [R2SiāGeR]Ė, remain exceedingly rare. Herein, we present a systematic investigation of silagermenides, synthesized ...
https://onlinelibrary.wiley.com/doi/10.1002/anie.202505940
7 months ago
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