The Surendranath Group 🥭
@interphases.org
📤 947
📥 179
📝 78
electrochemistry research group @ MIT
pinned post!
No 🔋⚡ELECTROCHEMSKY⚡🔋 starter pack? That's fine, we'll make our own.
go.bsky.app/7BokNKP
add a skeleton here at some point
about 1 year ago
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jo melville
10 days ago
please don't @ me like "actually cerium is unique among the lanthanides for its +4 oxidation state" ⚗️🧪
#chemsky
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Congrats Hai-Xu Wang! CO₂ hydrogenation to formate and NAD⁺ hydrogenation to NADH — long considered purely non-electrochemical heterolytic hydrogenations — can actually follow an electrochemical mechanism, coupling oxidative hydrogen oxidation (HOR) and reductive hydrogen reduction reactions (HRR)!
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Thermochemical heterolytic hydrogenation catalysis proceeds through polarization-driven hydride transfer - Nature Chemistry
Heterolytic hydrogenations are a key reaction class that includes CO2 reduction to formate and NADH regeneration, yet the mechanism remains unclear. Now it has been shown that this class of thermochemical reactions proceeds through an electrochemical mechanism, with polarization-driven, interfacial hydride transfer as the rate-determining step.
https://www.nature.com/articles/s41557-025-01939-0?utm_source=rct_congratemailt&utm_medium=email&utm_campaign=nonoa_20251009&utm_content=10.1038/s41557-025-01939-0
about 1 month ago
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Congratulations to Hye Won Chung and Dr. Hai-Xu Wang! Using hydrogen reduction reaction (HRR), where H2 interconverts w/ hydrides, they developed a potentiometric method to quantify molecular hydricity, applied it to substrates including formate & borohydrides, and investigated solvent-dependence.
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Reversible Interfacial Hydride Transfer as a Complementary Tool To Measure Molecular Hydricity
Hydride transfer is an essential elementary reaction across the chemical value chain, but there are limited methods available for quantifying thermodynamic hydricity (ΔGH–), particularly among main gr...
https://pubs.acs.org/doi/10.1021/jacs.5c09582
about 1 month ago
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Congrats Kunal!
add a skeleton here at some point
about 1 month ago
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Congrats Dr. Deiaa Harraz!
add a skeleton here at some point
about 1 month ago
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jo melville
3 months ago
13/ Come on SpongeBob! You know: I wungsten, you wungsten, he/she/me wungsten...
doi.org/10.1128/jb.1...
⚗️🧪
#chemsky
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Omnipath H2 aims to revolutionize the midstream hydrogen industry based on a technology developed in the Surendrath group. We congratulate the team for winning 2nd place at this year’s MIT Climate & Energy Prize.
7 months ago
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jo melville
11 months ago
59/ kemistry ⚗️🧪👍
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Helvetica Chimica Acta
7 months ago
Yogesh Surendranath @ChemistryMIT
@interphases.org
opens the Spring Meeting
#sm25
of
@swisschemistry.bsky.social
with ‚Using Electrochemistry to Understand and Control Thermochemical Catalysis‘
@unibe.ch
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jo melville
7 months ago
they did oxygen evolution on a hazelnut [to prove the point that it's meaningless it is to interpret electrocatalytic data from poorly defined complex electrode materials]
#chemsky
⚗️🧪
pubs.acs.org/doi/10.1021/...
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Electrocatalysis Goes Nuts
While searching for new nanoelectrocatalysts with outstanding performance, researchers often disregard the complexity and true usability of such materials. Here, it is argued that the chemical and str...
https://pubs.acs.org/doi/10.1021/acscatal.2c00123
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jo melville
7 months ago
112/
#chemsky
⚗️🧪
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Check out this MIT News page about our recent paper:
news.mit.edu/2025/surpris...
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Surprise discovery could lead to improved catalysts for industrial reactions
Upending a long-held supposition, MIT researchers discovered that a common catalyst works by cycling between two different forms. The finding could lead to improved catalysts for industrial reactions.
https://news.mit.edu/2025/surprise-discovery-could-mean-improved-catalysts-industrial-reactions-0403
8 months ago
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Jake Yeston
8 months ago
add a skeleton here at some point
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Jake Yeston
8 months ago
Great Perspective from Cathy Tway & Sorin Filip here too
www.science.org/doi/10.1126/...
add a skeleton here at some point
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Jake Yeston
8 months ago
Fascinating chemsky paper in
@science.org
today from
@interphases.org
meticulously revealing that vinyl acetate synthesis operates through tandem homogeneous and heterogeneous palladium catalysis 🧪
www.science.org/doi/10.1126/...
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Homogeneous-heterogeneous bifunctionality in Pd-catalyzed vinyl acetate synthesis
Presently, mechanistic paradigms in catalysis generally posit that the active species remains either homogeneous or heterogeneous throughout the reaction. In this work, we show that a prominent indust...
https://www.science.org/doi/10.1126/science.ads7913
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Congratulations our very own Deiaa Harraz, Kunal Lodaya, Bryan Tang for their new paper in Science! Check out our new paper titled Homogeneous-heterogeneous bifunctionality in Pd-catalyzed vinyl acetate synthesis
www.science.org/doi/10.1126/...
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Homogeneous-heterogeneous bifunctionality in Pd-catalyzed vinyl acetate synthesis
Presently, mechanistic paradigms in catalysis generally posit that the active species remains either homogeneous or heterogeneous throughout the reaction. In this work, we show that a prominent indust...
https://www.science.org/doi/10.1126/science.ads7913
8 months ago
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We have a new LinkedIn page! Check it out here
www.linkedin.com/company/sure...
8 months ago
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jo melville
8 months ago
[1/2] aromaticity question for
#chemsky
: consider this annular carbon allotrope C18. let's define p orbitals sigma-bonding tangential to the ring as p_z, those pi-bonding in the plane of the ring to be p_y, and those pi-bonding perpendicular to the plane of the ring to be p_x.
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Take a look at our new paper by Neil Razdan and Karl Westendorff as they develop an exciting new method to measure the potential of thermochemical catalysts supported on electrically insulating supports!
www.nature.com/articles/s41...
#chemsky
#echem
#echemsky
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Wireless potentiometry of thermochemical heterogeneous catalysis - Nature Catalysis
Interfacial polarization influences catalytic reactions occurring at solid–liquid interfaces, but its measurement was previously limited to conductive materials. Now redox-active molecules enable elec...
https://www.nature.com/articles/s41929-025-01308-7
8 months ago
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Dr Dan Shugar 🇨🇦
8 months ago
The Mango Industrial Complex, up to their usual tactics I see
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jo melville
8 months ago
85/ is it a literature procedure?
#chemsky
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Wolf-Peter Schill
9 months ago
I love it that in Australia you don't just buy a mango, but you can choose from about five varieties in any supermarket
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Justin Bui
10 months ago
Our article with
@interphases.org
on the role of ion management in enhancing performance for bipolar membranes in forward bias is now
#OpenAccess
as a part of
@natchemeng.bsky.social
’s
@natureportfolio.bsky.social
Anniversary issue! 🧪 Link:
www.nature.com/articles/s44...
#ChemSky
#CompChemSky
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Ion-specific phenomena limit energy recovery in forward-biased bipolar membranes - Nature Chemical Engineering
Forward-biased bipolar membranes (FB-BPMs), which recover potential from pH gradients through ion–ion recombination, show promise for application in sustainable devices. The authors use physics-based ...
https://www.nature.com/articles/s44286-024-00154-x
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x.com/meganj6E23/s...
👀👀👀👀 congrats Kenneth and Megan!!
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x.com
https://x.com/meganj6E23/status/1884332783964930462
10 months ago
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why not join the SURENDRANATH GROUP
add a skeleton here at some point
10 months ago
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Chris Constantine-Armstrong
10 months ago
Finally cleaned that image of Flasky.
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jo melville
10 months ago
Chemists actually love to do this (e.g. TiCl4→"tickle" or FOOF). The real way to piss off a chemist is to screw up a simple Lewis structure with a Texas carbon.
#chemsky
⚗️🧪
add a skeleton here at some point
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Paul Kempler
10 months ago
(Electro)chemsky! These students are available for hire beginning April or June 2025 and do not have to return to Eugene after completing their internship (
electrochemistry.uoregon.edu/masters-inte...
) Let us know if you'd like to see some resumes and please share for visibility 🧪⚡
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Class of 2025 – Oregon Center for Electrochemistry
https://electrochemistry.uoregon.edu/masters-internship-program/class-of-2025/
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At the end of the day, all chemists are either nuclear chemists or electrochemists.
#chemsky
add a skeleton here at some point
10 months ago
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if you're following us, you should be following
@annawuttig.bsky.social
for more great interfacial electrochemistry! (and check out our 🔋⚡ELECTROCHEMSKY⚡🔋 starter pack for a great collection of echem researchers of all flavors!)
go.bsky.app/7BokNKP
add a skeleton here at some point
10 months ago
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The Surendranath Group 🥭
Anna Wuttig
10 months ago
My lab's next paper is out in Angewandte Chemie! Disorder activates graphitic carbon for echem rxns—but can we distinguish it in situ? Varying disorder shows different electric-field IR responses! w/ Ry, Ben & calculations from Arpan in Galli Group
onlinelibrary.wiley.com/doi/10.1002/...
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jo melville
11 months ago
thinking about one of my favorite Manhattan Project stories, when some klutz spilled ¼ of the world supply of plutonium on a copy of the Chicago Tribune and a team of chemists had to figure out how to get it back out (they digested the newspaper in nitric acid, using a technique called wet ashing)
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Justin Bui
11 months ago
My final first author paper🧪, a collaborative study with
@interphases.org
on the importance of ion-management in forward-biased bipolar membranes ➕➖, is now published in
@natureportfolio.bsky.social
Chemical Engineering! Read here:
rdcu.be/d4hPk
🧵 below with more detail!
#GreenSky
#Chemistry
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Ion-specific phenomena limit energy recovery in forward-biased bipolar membranes
Nature Chemical Engineering - Forward-biased bipolar membranes (FB-BPMs), which recover potential from pH gradients through ion–ion recombination, show promise for application in sustainable...
https://rdcu.be/d4hPk
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The Surendranath Group 🥭
jo melville
11 months ago
63/ spotted on a campus bulletin board at MIT
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Our postdoc HX has achieved rank #201 on Chemdle over the last month, with 19 wins on 34 games played 💅
11 months ago
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jo melville
11 months ago
life hack: it's deliberately hard to find but you can find toggles to disable those bullshit epdf readers. here is the link for Wiley journals:
content.readcube.com/html/epdf_se...
add a skeleton here at some point
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Check out our collaboration with the Bullock group at PNNL! Travis, Vennela and Deiaa's exciting new paper on the rate-potential scaling relationships of adsorbed molecular iron macrocycle complexes for aqueous ORR is now online at ACS Catalysis 😎🤿
pubs.acs.org/doi/abs/10.1...
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Shallow Rate-Redox Potential Scaling in Aqueous Molecular Oxygen Reduction Electrocatalysis Across a Family of Iron Macrocycles
Rate-overpotential scaling relationships have been employed widely to understand trends in oxygen reduction reaction (ORR) electrocatalysis by dissolved metal macrocycles in organic electrolytes. Simi...
https://pubs.acs.org/doi/abs/10.1021/acscatal.4c06561
11 months ago
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"Yes please i would like a tube of SWAK. Please give me a can of PURE GOOP" - Statements dreamed up by the utterly Deranged
add a skeleton here at some point
11 months ago
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jo melville
12 months ago
#chemsky
history anecdote: Both spellings were common in the US in 1886 when Charles Hall invented his eponymous process and founded Alcoa. Hall favored "aluminum" over "aluminium" in marketing to evoke associations with nobler metals like platinum, and Americans have used his spelling ever since.
add a skeleton here at some point
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jo melville
12 months ago
this old meme I made is actually about the mechanism of action of aqua regia dissolution of gold. basically, HNO3 can oxidize gold but can't complex it, so it can only dissolve a bit. HCl can complex gold ions but can't oxidize gold. it takes the two together in a mixture to fully dissolve gold!
add a skeleton here at some point
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jo melville
12 months ago
*eye twitching* "i don't need a personal rotavap... i DON'T NEED a personal rotavap"
add a skeleton here at some point
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jo melville
12 months ago
800 °C molten-salt electrolysis of phosphate to white phosphorus, aka "I melted rocks to lava and zapped them with lightning until they caught fire and exploded"
pubs.acs.org/doi/full/10....
add a skeleton here at some point
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The Surendranath Group 🥭
Battery Burn Book
12 months ago
We are working on a glossary of electrochemistry terms at the link in our bio. What battery definitions would you like to see?
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The Surendranath Group 🥭
Jake Yeston
12 months ago
🧵
add a skeleton here at some point
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The Surendranath Group 🥭
jo melville
12 months ago
36/ when my students ask me why units are important
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The Surendranath Group 🥭
jo melville
12 months ago
43/ phase diagram of savory foods
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A Song of Iodine and Fluorine
12 months ago
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we've been diligently adding folks to this over the past few weeks — if you've subscribed previously, please consider checking again for some fresh new faces!
add a skeleton here at some point
12 months ago
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Paul Kempler
12 months ago
Applications are open for the 6th cohort of the Electrochemistry Masters Internship Program! If you (or any undergraduates you know) are interested in a cleantech career related to electrochemistry this is a unique opportunity:
electrochemistry.uoregon.edu/masters-inte...
⚡chemsky
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M.S. Internship Program Flyer – Oregon Center for Electrochemistry
https://electrochemistry.uoregon.edu/masters-internship-program-flyer/
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Anne Fahrner
12 months ago
Hey
#chemsky
#polymersky
#Academicsky
and
#ChemE
I'm currently a junior (in chemical engineering) at the University of Akron. Our president, trying to eliminate the university debt, recently proposed letting go of some professors, primarily in STEM. As of right now, part of his plan appears to be:🧵
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