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New insights into primary and secondary coordination sphere effects in Rh(I) dimers with NIR emission - published in
@angewandtechemie.bsky.social
Huge thanks to
@wengeroliver.bsky.social
for exceptional mentorship and Giacomo Morselli for great collaboration
doi.org/10.1002/anie.6066376
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Controlling NearāInfrared FluorescenceātoāPhosphorescence Ratios and Triplet Lifetimes in Rhodium(I) Dimers via Primary and Secondary Coordination Sphere Effects
RhI dimers with bridging aryl isocyanide and di-phosphine ligands show NIR-I or NIR-II fluorescence/phosphorescence, depending on the ligands and conformational rigidity at the Rh2 core. Rh-Rh intera...
https://doi.org/10.1002/anie.6066376
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