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Metal-organic framework research at Kiel University.
🔬 Serendipity meets MOF science! In an unexpected discovery, Niklas Ruser reports the synthesis of a layered coordination polymer, [Ce(CH3COO)(SO4)(H2O)2]n -
#Chemistry
#MOF
👉 Read:
journals.iucr.org/e/issues/202...
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Crystal structure of poly[μ3-acetato-diaqua-μ3-sulfato-cerium(III)]: serendipidous synthesis of a layered coordination polymer exhibiting interlayer O—H⋯O hydrogen bonding
In the crystal structure of the title compound, the CeIII cations are ninefold coordinated and linked into chains via the acetate anions and are further connected into layers by the sulfate dianions.
https://journals.iucr.org/e/issues/2025/02/00/hb8117/index.html
over 1 year ago
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Bastian Achenbach unravels the complex synthesis-structure-property relationships of aluminum hydroxy acetates, introducing novel porous materials like CAU-55-OH & CAU-65. 💡🔬
#Chemistry
#MaterialsScience
#MOF
👉 Read:
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
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Unlocking the Chemical and Structural Complexity of Aluminum Hydroxy Acetates: from Commodity Chemicals to Porous Materials
A high-throughput investigation involving more than 330 reactions in the system Al3+/CH3COOH/NaOH/H2O permitted the elucidation of the synthesis-structure relationship and allowed us to shed light on...
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202403634
over 1 year ago
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