@lutzackermann.bsky.social
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Blue light for bluesky: Ru-catalyzed sec-alkylations: well done 👍 Yulei et al.
www.cell.com/chem/fulltex...
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Ruthenaphoto-catalyzed ortho-C−H alkylation with secondary alkyl halides: SET-enabled ruthenium(II/III/IV) manifold
Ruthenium-catalyzed meta-C(sp2)–H alkylations in the presence of secondary and tertiary alkyl halides are known to proceed through a radical pathway. However, the mechanism behind ruthenium-catalyzed ortho-C(sp2)–H alkylations remained thus far elusive. Now, we provide evidence for the ortho-alkylation to proceed via a one-electron radical pathway as supported by detailed experimental and computational DFT studies in terms of a ruthenium(II/III/IV) regime.
https://www.cell.com/chem/fulltext/S2451-9294(24)00632-6?_returnURL=https%3A%2F%2Flinkinghub.elsevier.com%2Fretrieve%2Fpii%2FS2451929424006326%3Fshowall%3Dtrue
about 1 year ago
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Thank you very much for the hospitality and great organization @ISCHA2024 in Bombay
over 1 year ago
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reposted by
Ackermann Lab
over 1 year ago
We’re happy to announce our presence on Bluesky. Follow us
@catalysis-lab.bsky.social
for updates, insights, and discoveries!
#Chemistry
#Catalysis
#science
website at
www.ackermann.chemie.uni-goettingen.de
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The Ackermann Group
https://www.ackermann.chemie.uni-goettingen.de/
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reposted by
Jake Yeston
over 1 year ago
Hey folks, Science is hiring a geo editor (ideally seismology)--pls spread the word! 🧪⚒️🌋🌍💎 earthsky
recruiting.ultipro.com/AME1123ASEM/...
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https://recruiting.ultipro.com/AME1123ASEM/JobBoard/07f12c2c-f20e-42f2-b442-dbab6fe420be/OpportunityDetail?opportunityId=4d84f7c4-e3c5-41f5-9851-d17279dc864e
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