Jonas Oliver Wenzel
@jonasoliverwenzel.bsky.social
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📥 180
📝 9
PostDoc BreherGroup @KIT Inorganic / Organic / Photochemistry
Are you interested in radical
#chemistry
or redox-active ligands? New work by
@brehergroup.bsky.social
about the isolation of a stable radical dianion is now in early view
@helvchimacta.bsky.social
as part of a special issue dedicated to Prof. Dr. Armido Studer.
#chemsky
doi.org/10.1002/hlca...
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Isolation of a Monomeric Bis(pyridylimino) Isoindolide (BPI) Radical Dianion and Further Insights Into Structures of Reduced BPI Compounds
This article reports on the isolation of a monomeric compound with a dianionic singly reduced bis(pyridylimino) isoindolide (BPI) ligand and elaborated discussions on the structure of reduced BPIs.
https://doi.org/10.1002/hlca.202500138
21 days ago
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New paper now out in Early View
@angewandtechemie.bsky.social
! We
@brehergroup.bsky.social
describe radical
#photochemistry
of main group
#organometallics
with visible light. With our article we want to make the described concept accessible to a broader
#chemistry
community.
#Chemsky
5 months ago
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reposted by
Jonas Oliver Wenzel
Breher Research Group
5 months ago
Very nice group excursion of the Hinz and Breher lab today! Many thanks to all involved 👍👍👍
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Had a wonderful time at
#EuCOMC
2025 in Bern! Thank you
@evaheviagroup.bsky.social
and
@albrecht-lab.bsky.social
for organizing a really great conference!
add a skeleton here at some point
5 months ago
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Are you interested in Main Group Photochemistry? Check out our recent Review about E-C bond photolysis 👇
add a skeleton here at some point
7 months ago
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reposted by
Jonas Oliver Wenzel
Breher Research Group
8 months ago
#TopViewedArticle
👍 We are delighted to share that our work, published in EurJIC
@wiley.com
, has ranked within the top 10% of most-viewed papers published by the journal in 2023 👉
doi.org/10.1002/ejic...
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Synthesis and Characterization of Bis(pyridylimino)isoindolide Alkali Metal Complexes in Three Redox States
This work reports on the synthesis and characterization of alkali metal complexes of BPI and Me2BPI in reduced oxidation states. CV, EPR and XRD studies revealed detailed information about the unknow...
https://doi.org/10.1002/ejic.202300315
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reposted by
Jonas Oliver Wenzel
Breher Research Group
8 months ago
The first mono ortho-phenylene bridged Al/P FLP was synthesized and characterized. Its reactivity was probed against several small molecules. Thanks to Melina Dianas 👍
doi.org/10.1002/ejic...
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Reactivity of an ortho‐Phenylene‐bridged Al/P Frustrated Lewis Pair Towards Small Molecules
Frustrated Lewis Pairs (FLPs) as ambiphilic molecules are prone to activate small molecules and are in the focus of interest for many years. In this paper, we present the first ortho-phenylene bridge...
https://doi.org/10.1002/ejic.202500174
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reposted by
Jonas Oliver Wenzel
Breher Research Group
8 months ago
A detailed study on the reactivity of ambiphilic metallacycles is presented. Thanks to
@felixkraemer.bsky.social
,
@pascalweisenb.bsky.social
and
@isra-group.bsky.social
)! Have a look at the paper 👉
doi.org/10.1002/ejic...
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Stabilities and Limitations in the Reactivity of Phosphorus Ylide‐Based Aluminum‐ and Gallium‐Carbon Ambiphiles − A Combined Experimental and Computational Approach
The unexpected reactivity and stability limits of phosphorus ylide-based aluminum- and gallium-carbon ambiphiles are described. While the previously published t-butyl-substituted compound (2-{AltBu2}...
https://doi.org/10.1002/ejic.202500165
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reposted by
Jonas Oliver Wenzel
Breher Research Group
10 months ago
Many thanks to
@joshabbenseth.bsky.social
and Frank Tambornino for highlighting our collaborative study on the organometallic and photochemistry of R2Al(BPI) complexes in „Trendbericht Anorganische Chemie 2025“ 👍👍👍
onlinelibrary.wiley.com/doi/10.1002/...
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reposted by
Jonas Oliver Wenzel
Breher Research Group
10 months ago
Let’s start here with our last post from the other timeline: Many thanks to the Podlech group for letting us be part of this nice study: A Stable Carbon‐Centered Radical Showing Six Amphoteric Redox States. Now out in Chem Eur J.
chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...
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A Stable Carbon‐Centered Radical Showing Six Amphoteric Redox States
A fully conjugated system built by alternate fusion of four benzene and three cyclopentadiene rings is a further rare example of an air- and moisture-stable carbon-centered hydrocarbon radical. It wa...
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202403670
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