Paul Davies (@syncat.bsky.social)

Nice to see this work out in Organometallics doi.org/10.1021/acs.... arising from new azophosphine ligands developed by Andy Jupp's group at Birmingham, and marking our our first foray into using ReactIR to study catalysis.

loading . . .

Tuning the Electronic Properties of Azophosphines as Ligands and Their Application in Base-Free Transfer Hydrogenation Catalysis The design and tuning of new ligands is crucial for unlocking new reactivity at transition metal centers. Azophosphines have recently emerged as a new class of 1,3-P,N ligands in ruthenium piano-stool... https://doi.org/10.1021/acs.organomet.4c00302